Chemistry Letters

Synthesis and characterization of a membrane-spanning porphinatoiron (II).

E Tsuchida, E Hasegawa, T Komatsu, T Nakata…

Index: Tsuchida, Eishun; Hasegawa, Etsuo; Komatsu, Teruyuki; Nakata, Taisaku; Nishide, Hiroyuki Chemistry Letters, 1990 , # 3 p. 389 - 392

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Citation Number: 14

Abstract

A new tetraphenylporphinatoiron (II) having a couple of four amphiphilic chains on both sides of the porphyrin ring plane, 5, 10, 15, 20-tetra (2′, 6′-di (20 ″-hydroxy-2 ″, 2 ″- dimethylicosanoyloxy) phenyl) porphinatoiron, was synthesized as a model for membrane intrinsic proteins. It was well incorporated in the liposomal bilayer and characterized. The complex with 1-dodecylimidazole embedded in phospholipid bilayer formed an oxygen ...

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