The Journal of Organic Chemistry

Reaction of singlet oxygen with enamino carbonyl systems. A general method for the synthesis of. alpha.-keto derivatives of lactones, esters, amides, lactams, and …

HH Wasserman, JL Ives

Index: Wasserman, Harry H.; Ives, Jeffrey L. Journal of Organic Chemistry, 1985 , vol. 50, # 19 p. 3573 - 3580

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Citation Number: 79

Abstract

-_ _ conversion of a ketone to an a-diketone, for example, has been employed in the synthesis of colchicine, ls strychnine, lb and other natural products. There have been important applications of a-keto lactam formation in synthesis, ranging from the preparation of senecio2 and vasicine al-kaloid~~ to the synthesis of P-lactams4 and derivatives of penams and cephams. 6 In addition, there is intrinsic

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