High-Yield Method for the Preparation of 1, 3, 4, 5-Tetrahydro-7-methoxy-2 H-1-benzazepin-2-one with Excellent Regio-and Stereoselectivity

FY Piao, YZ Xie, WB Zhang, W Zhang…

Index: Piao, Feng-Yu; Xie, Yu-Zhong; Zhang, Wen-Bin; Zhang, Wei; Han, Rong-Bi Synthetic Communications, 2013 , vol. 43, # 14 p. 1920 - 1930

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Abstract

View all references ] According to the mechanism of the Beckmann rearrangement, 6-methoxy-3,4-dihydro-naphthalene-1(2H)-one oxime should produce the title compound. However, because of the similar size of the groups on both ends of the C˭N double bond [ 8 8. Yan , P. ; Batamack , P. ; Prakash , GKS ; Olah , GA Gallium(III)–triflate–catalyzed Beckmann rearrangement . Catal. Lett. 2005 , 103 , 165 – 168 . [CrossRef], [Web of Science ®] View ...

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