Sustainable Heterogeneous Platinum Catalyst for Direct Methylation of Secondary Amines by Carbon Dioxide and Hydrogen

…, SMA Siddiki, W Onodera, K Shimizu

Index: Kon, Kenichi; Siddiki, S. M. A. Hakim; Onodera, Wataru; Shimizu, Ken-Ichi Chemistry - A European Journal, 2014 , vol. 20, # 21 p. 6264 - 6267

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Citation Number: 24

Abstract

Abstract Pt and MoO x co-loaded TiO 2 is found to be highly effective for direct methylation of aliphatic and aromatic secondary amines by CO 2 and H 2 under solvent-free conditions. This is the first additive-free and reusable heterogeneous catalytic system with acceptable turnover number.