Tetrahedron

Efficient chemoselective alcohol oxidation using oxygen as oxidant. Superior performance of gold over palladium catalysts

A Abad, C Almela, A Corma, H García

Index: Abad, Alberto; Almela, Carles; Corma, Avelino; Garcia, Hermenegildo Tetrahedron, 2006 , vol. 62, # 28 p. 6666 - 6672

Full Text: HTML

Citation Number: 170

Abstract

Gold nanoparticles supported on nanocrystalline ceria (Au/CeO2) is a general, air-and moisture-stable, commercial catalyst for the atmospheric pressure, solventless oxidation of aromatic, primary and secondary alcohols to the corresponding benzaldehyde or ketone compound. Aliphatic primary alcohols are oxidized to the corresponding alkyl ester and aliphatic secondary alcohols are oxidized to ketones. Conversions and product yields are ...

Related Articles:

Iridium??catalyzed direct dehydroxylation of alcohols

[Huang, Jian-Lin; Dai, Xi-Jie; Li, Chao-Jun European Journal of Organic Chemistry, 2013 , # 29 p. 6496 - 6500]

Pd/C??Catalyzed Transfer??Hydrogenation of Benzaldehydes to Benzyl Alcohols Using Potassium Formate as the Selective Hydrogen Donor

[Baidossi, Mubeen; Joshi, Ashutosh V.; Mukhopadhyay, Sudip; Sasson, Yoel Synthetic Communications, 2004 , vol. 34, # 4 p. 643 - 650]

Reaction of o-benzoquinone bisacetals with organolithiums. A novel route to substituted veratroles

[Kikuchi, Yoshiyuki; Hasegawa, Yoko; Matsumoto, Masakatsu Tetrahedron Letters, 1982 , vol. 23, # 21 p. 2199 - 2202]

Der Nachweis eines Radikalketten??Mechanismus für die Knabe??Reaktion von 1, 2??Dihydro??2??methylpapaverin

[Langhals, Elke; Langhals, Heinz; Ruechardt, Christoph Chemische Berichte, 1984 , vol. 117, # 4 p. 1436 - 1454]

More Articles...