Reactions of Group IV Organometallic Compounds. I. The Reaction of Trimethylsilyldialkylamines with β-Propiolactone

K Itoh, S Sakai, Y Ishii

Index: Itoh,K. et al. Journal of Organic Chemistry, 1966 , vol. 31, p. 3948 - 3951

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Citation Number: 23

Abstract

The reaction between p-propiolactone and trimethylsilyldialkylamines was performed by adding p-propiolactone (10 mmoles) to trimethylsilyldialkylamine-(12 mmoles) dissolved in ethylene dichloride (2 ml), allowing the mixture to stand for 24 hr at 80, and distilling the product under reduced pressure. The reaction products show a strong infrared absorption at 1720 cm-l which could be assigned as the