Journal of fluorine chemistry

Photochemical bromination of arenes. 2. Fluorobenzene derivatives [1]

R Bolton, ESE Owen

Index: Bolton, Roger; Owen, Elaine S. E. Journal of Fluorine Chemistry, 1990 , vol. 46, # 3 p. 393 - 406

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Citation Number: 6

Abstract

Abstract Photochemically induced reaction of fluorobenzene and a range of polyfluorobenzenes, both in an excess of the arene and with fluorotrichloromethane as solvent, gave isolable adducts only with fluorobenzene, the isomeric difluorobenzenes, and in very small yield with 1, 3, 5-tri-fluorobenzene. These adducts were identified by combustion analysis, mass spectrometry, and nmr techniques (1 H, 19 C, 19 F). In every ...