Über Reaktionen der o-Chinolacetate des Vanillins und Isovanillins, 1. Mitt.

F Wessely, M Grossa

Index: Wessely,F.; Grossa,M. Monatshefte fuer Chemie, 1966 , vol. 97, p. 570 - 578

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Citation Number: 8

Abstract

Abstract The reaction of NaCN with 2-methoxy-4-formyl-o-quinol acetate (1) and 2-methoxy- 5-formyl-o-quinol acetate (2) differs fundamentally from that with the corresponding dimethyl substituted quinol acetates. With 1 the type of reaction products formed depends to a great extent on the solvent used: in methanol 1 yields 3-hydroxy-4-cyano-benzoic acid methylester, in DMF, however, 2-cyano-3-methoxy-4-hydroxybenzaldehyde. The ...