Synthesis of prenylated indoles
E Wenkert, EC Angell, VF Ferreira…
Index: Wenkert, Ernest; Angell, E. Charles; Ferreira, Vitor F.; Michelotti, Enrique L.; Piettre, Serge R.; et al. Journal of Organic Chemistry, 1986 , vol. 51, # 12 p. 2343 - 2351
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Citation Number: 74
Abstract
Interaction of magnesium indolates and allyl oxides in the presence of bis (tripheny1phosphine) nickel dichloride results in indole P-allylation, except in cases involving highly substituted indoles and allyl alcohols. This method permits the@- prenylation of indole and a-prenylation of ketones (by way of their magnesium enaminates). Base-induced interaction of ethynyldimethylcarbinyl chloride and indole under a variety of ...
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