Oxidation of 2-dialkylaminomethyl-4, 6-di-tert-butylphenols

IS Belostotskaya, VB Vol'eva, NL Komissarova…

Index: Belostotskaya; Vol'eva; Komissarova; Dekaprilevich; Khrustalev; Karmilov; Ershov Russian Chemical Bulletin, 1997 , vol. 46, # 7 p. 1272 - 1280

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Abstract

Abstract Oxidative transformations of 2-dialkylaminomethyl-4, 6-di-tert-butylphenols depend on the nature of the oxidant, the character of the substituents at the nitrogen atom, and the medium. A mechanism of the oxidation of these compounds is suggested. The molecular structure of the compound obtained as a result of oxidative trimerization of 2- dimethylaminomethyl-4, 6-di-tert-butylphenol was established by X-ray structural analysis.

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