1, 3-Dialkyltriazenes: tautomeric equilibria and rates and products of decomposition

…, BD Wladkowski, AF Mehl, MJ Cleveland…

Index: Smith, Richard H.; Wladkowski, Brian D.; Mehl, Andrew F.; Cleveland, Michael J.; Rudrow, Elizabeth A.; et al. Journal of Organic Chemistry, 1989 , vol. 54, # 5 p. 1036 - 1042

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Citation Number: 26

Abstract

Unsymmetrical 1, 3-dialkyltriazenes, RN= NNHR', exist as a tautomeric mixture because of rapid proton exchange between nitrogens 1 and 3. Hydronium ion catalyzed decomposition of these triazenes gives rise to a mixture of alkanediazonium ions, RN2+ and R'N2+, and the corresponding primary amines. The objective of this study was to determine the factors that influence partitioning between the two pathways originating from the two tautomers. A ...

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