Chemistry Letters

Reactions of benzene vapor-calcium atom with organic halides and carbonyl compounds

K Mochida, H Takeuchi, Y Hiraga, H Ogawa

Index: Mochida, Kunio; Takeuchi, Hidenori; Hiraga, Yoo; Ogawa, Hiroyasu Chemistry Letters, 1984 , p. 1989 - 1992

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Abstract

Reactions of benzene vapor-calcium atom with organic halides and carbonyl compounds were examined. Benzene vapor-calcium atom reacted with organic halides (RX) to give phenyl-substituted products (PhR) and reduced products (RH). The reactions of benzene vapor-calcium atom with ketones (RR′ CO) or benzaldehyde gave two kinds of alcohol PhRR′ COH and RR′ CHOH, or Ph 2 CHOH and PhCH 2 OH, respectively

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