Convenient Transformation of Benzyl Alcohol into Its Corresponding Selenide Using the Selenolate Anion-Aluminum Chloride Combination System.

H Abe, A Yamasaki, H Fujii, T HARAYAMA

Index: Abe, Hitoshi; Yamasaki, Akira; Fujii, Hiroyuki; Harayama, Takashi Chemical and Pharmaceutical Bulletin, 1996 , vol. 44, # 12 p. 2223 - 2226

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Citation Number: 7

Abstract

2224 Table 2. Reaction of Various Alcohols with the Methyl Selenolate Anion MeSeSeMe NaBH, (10 moleq) AlCl, (10 moleq) alcohol selenide CH,CN 12–15 Yieldº) Entry Alcohol 驚 Product : O- SeMe 35 í 12 72 ( 3) LGS BBB 3 MMMM 4,5 _b) GGG SeMe - - - - Se Me 4,5 ( )-- () 67 (15) - SS. 4. () S kkkk 15 30 (12) a) Values in parentheses are % yields of the alcohols recovered. b) A comple* mixture was obtained. 0 (92) 0 ( 8) Table 3, Reaction of Carbonyl ...

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