The Cleavage of β-Oxypropionitriles with Lithium Aluminum Hydride1

LM Soffer, EW Parrotta

Index: Soffer; Parrotta Journal of the American Chemical Society, 1954 , vol. 76, p. 3580,3583

Full Text: HTML

Citation Number: 17

Abstract

LiAlHd RO (CH2) zCN ___f ROH+ I< O (CH~) JSH:, f C! &CH~ CIILS€ IL propionitriles has show11 that the cleavage is general and occurs with an evolution of hydrogen. The general instability of fi-alkoxypropionitriles to heat and aqueous base is well known. 2 Moe, Miller and Buckley3 have reported that cleavage at the ether linkage resulted when the hydrolysis of the P-cyanoethyl ethers of certain polysaccharides was attempted in alkaline solution. ...

Related Articles:

Chromyl complexes in the direct epoxidation of alkenes

[Miyaura, N.; Kochi, J. K. Journal of the American Chemical Society, 1983 , vol. 105, # 8 p. 2368 - 2378]

Mechanism of anodic cleavage of benzyl ethers

[Boyd, Jean W.; Schmalzl, Paul W.; Miller, Larry L. Journal of the American Chemical Society, 1980 , vol. 102, # 11 p. 3856 - 3862]

Construction of the bicyclo [3.1. 0] hexane template of a conformationally locked carbocyclic adenosine via an olefin keto-carbene cycloaddition

[Glover, Stephen A.; Golding, Stephen L.; Goosen, Andre; McCleland, Cedric W. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 10 p. 2479 - 2483]

1, 3-Dialkyltriazenes: tautomeric equilibria and rates and products of decomposition

[Smith, Richard H.; Wladkowski, Brian D.; Mehl, Andrew F.; Cleveland, Michael J.; Rudrow, Elizabeth A.; et al. Journal of Organic Chemistry, 1989 , vol. 54, # 5 p. 1036 - 1042]

Bakers' yeast mediated synthesis of 4-deoxy-D-lyxo-hexopyranose (4-deoxy-D-mannose)

[Fronza, Giovanni; Fuganti, Claudio; Grasselli, Piero; Servi, Stefano Journal of Organic Chemistry, 1987 , vol. 52, # 10 p. 2086 - 2089]

More Articles...