Kinetic solvent effects on hydrogen abstraction reactions from carbon by the cumyloxyl radical. The importance of solvent hydrogen-bond interactions with the …

M Salamone, I Giammarioli, M Bietti

Index: Salamone, Michela; Giammarioli, Ilaria; Bietti, Massimo Journal of Organic Chemistry, 2011 , vol. 76, # 11 p. 4645 - 4651

Full Text: HTML

Citation Number: 18

Abstract

A kinetic study of the hydrogen atom abstraction reactions from propanal (PA) and 2, 2- dimethylpropanal (DMPA) by the cumyloxyl radical (CumO•) has been carried out in different solvents (benzene, PhCl, MeCN, t-BuOH, MeOH, and TFE). The corresponding reactions of the benzyloxyl radical (BnO•) have been studied in MeCN. The reaction of CumO• with 1, 4- cyclohexadiene (CHD) also has been investigated in TFE solution. With CHD a 3-fold ...

Related Articles:

Chromyl complexes in the direct epoxidation of alkenes

[Miyaura, N.; Kochi, J. K. Journal of the American Chemical Society, 1983 , vol. 105, # 8 p. 2368 - 2378]

Mechanism of anodic cleavage of benzyl ethers

[Boyd, Jean W.; Schmalzl, Paul W.; Miller, Larry L. Journal of the American Chemical Society, 1980 , vol. 102, # 11 p. 3856 - 3862]

Construction of the bicyclo [3.1. 0] hexane template of a conformationally locked carbocyclic adenosine via an olefin keto-carbene cycloaddition

[Glover, Stephen A.; Golding, Stephen L.; Goosen, Andre; McCleland, Cedric W. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 10 p. 2479 - 2483]

1, 3-Dialkyltriazenes: tautomeric equilibria and rates and products of decomposition

[Smith, Richard H.; Wladkowski, Brian D.; Mehl, Andrew F.; Cleveland, Michael J.; Rudrow, Elizabeth A.; et al. Journal of Organic Chemistry, 1989 , vol. 54, # 5 p. 1036 - 1042]

Bakers' yeast mediated synthesis of 4-deoxy-D-lyxo-hexopyranose (4-deoxy-D-mannose)

[Fronza, Giovanni; Fuganti, Claudio; Grasselli, Piero; Servi, Stefano Journal of Organic Chemistry, 1987 , vol. 52, # 10 p. 2086 - 2089]

More Articles...