A kinetic and mechanistic study of the self-reaction and reaction with HO2 of the benzylperoxy radical

…, MD Hurley, MA Dearth, TJ Wallington

Index: Noziere, Barbara; Lesclaux, Robert; Hurley, Michael D.; Dearth, Mark A.; Wallington, Timothy J. Journal of Physical Chemistry, 1994 , vol. 98, # 11 p. 2864 - 2873

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Citation Number: 59

Abstract

-C&sCHO+ C&CH2OH+ 0 2 (3b), and CaHsCH202+ HOz-C&CHzOOH+ 0 2 (4) have been investigated using two complementary techniques: flash photolysis/UV absorption for kinetic measurements and continuous photolysis/FTIR spectroscopy for end-product analyses and branching ratio determinations. The reaction of chlorine atoms with toluene was found to yield benzyl radicals exclusively and was used to generate benzylperoxy radicals in ...

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