Homogeneous catalytic oxidation of light alkanes: CC bond cleavage under mild conditions

EG Chepaikin, AP Bezruchenko, GN Menchikova…

Index: Chepaikin; Bezruchenko; Menchikova; Moiseeva; Gekhman Kinetics and Catalysis, 2010 , vol. 51, # 5 p. 666 - 671

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Abstract

Abstract The combined oxidation of CO and C 2–C 4 alkanes (associated petroleum gas and natural gas components) under the action of oxygen in trifluoroacetic acid solutions in the presence of rhodium and copper chlorides was accompanied by the oxidative degradation of CC bonds in a hydrocarbon chain with the formation of carbonyl compounds, alcohols, and esters. For butane and isobutane, the reaction path with CC bond cleavage ...

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