Journal of organometallic chemistry

SnCl 2 mediated efficient N, N-dialkylation of azides to tertiary-amine via potential stannaimine intermediate

UK Roy, S Roy

Index: Roy, Ujjal Kanti; Roy, Sujit Journal of Organometallic Chemistry, 2006 , vol. 691, # 8 p. 1525 - 1530

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Citation Number: 3

Abstract

Under the aegis of anhydrous stannous chloride, the reaction of aliphatic or aromatic azides with organic halides (alkyl, benzyl, propargyl) lead to the formation of corresponding N,N-dialkylamines in good to excellent yields. Additional Pd(0) catalyst further enhances the yield in the case of

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