Electrocarboxylation of chlorinated aromatic compounds

D Golinske, J Voss, G Adiwidjaja

Index: Golinske, Dirk; Voss, Juergen; Adiwidjaja, Gunadi Collection of Czechoslovak Chemical Communications, 2000 , vol. 65, # 6 p. 862 - 880

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Citation Number: 18

Abstract

Abstract Chorinated benzenes (1, 4), biphenyls (6, 9), dibenzofurans (10, 15, 17, 18), 2- chlorodibenzo [1, 4] dioxine (24) and 1-chloronaphthalene (26) as well as dibenzofuran (12) and naphthalene (27) themselves were transformed into carboxylic acids by galvanostatic electroreduction in the presence of carbon dioxide (" electrocarboxylation"). Dry DMF was used as solvent, zinc or stainless steel as cathode and magnesium as a sacrificial anode ...

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