Dioxiranes. 20. Preparation and properties of some new dioxiranes

RW Murray, M Singh, R Jeyaraman

Index: Murray, Robert W.; Singh, Megh; Jeyaraman, Ramasubbu Journal of the American Chemical Society, 1992 , vol. 114, # 4 p. 1346 - 1351

Full Text: HTML

Citation Number: 62

Abstract

Abstract: The in situ method for producing dioxiranes has been modified to permit the isolation in ketone solution of some nonvolatile dioxiranes. The dioxiranes have been characterized spectroscopically and, in some cases, by chemical reactions. ... Introduction In 1985 we described* the isolation in solution of dimethyl- dioxirane (1) as well as some related dioxiranes. Dimethyl- dioxirane is a powerful oxygen atom donor, and the availability of this unique reagent in solution ...

Related Articles:

Bi (OTf) 3-catalyzed Baeyer–Villiger oxidation of carbonyl compounds with m-CPBA

[Alam, M. Mujahid; Varala, Ravi; Adapa, Srinivas R. Synthetic Communications, 2003 , vol. 33, # 17 p. 3035 - 3040]

Supported sulfonic acid as green and efficient catalyst for Baeyer–Villiger oxidation with 30% aqueous hydrogen peroxide

[Piscopo, Calogero G.; Loebbecke, Stefan; Maggi, Raimondo; Sartori, Giovanni Advanced Synthesis and Catalysis, 2010 , vol. 352, # 10 p. 1625 - 1629]

Caprolactam from Renewable Resources: Catalytic Conversion of 5??Hydroxymethylfurfural into Caprolactone

[Buntara, Teddy; Noel, Sebastien; Phua, Pim Huat; Melian-Cabrera, Ignacio; De Vries, Johannes G.; Heeres, Hero J. Angewandte Chemie - International Edition, 2011 , vol. 50, # 31 p. 7083 - 7087]

A convenient, one-pot conversion of secondary alcohols to esters via a tandem oxidation-Baeyer-Villiger sequence

[Morin-Fox, Michelle L.; Lipton, Mark A. Tetrahedron Letters, 1992 , vol. 33, # 39 p. 5699 - 5700]

Oxidation of cyclohexane with hydrogen peroxide over β-zeolites with various Si/Al ratios

[Ohno, Ryohei; Taniya, Keita; Tsuruya, Shigeru; Ichihashi, Yuichi; Nishiyama, Satoru Catalysis Today, 2013 , vol. 203, p. 60 - 65]

More Articles...