Russian Journal of Organic Chemistry

Induced halogenation of alkyl cyclohexenyl ketones involving metal halides, hydrohalogenic acids, and hydrogen peroxide

OA Sadygov, KM Alimardanov

Index: Sadygov; Alimardanov Russian Journal of Organic Chemistry, 2009 , vol. 45, # 2 p. 166 - 172

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Abstract

Abstract The induced halogenation and hydroxyhalogenation of alkyl cyclohexenyl ketones in a system [MHlg+ HHlg or HHlg]-H 2 O 2 or in NaOCl was performed and optimum reaction conditions were established. Under mild conditions the electrophilic addition of the halogen or the acid occurred at the multiple bond of the ring with the formation of the corresponding dihalo or hydroxyhalo derivatives of cycloaliphatic ketones. From the compounds obtained ...

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