Solvolysen von [Cycloocten??(4)??yl??(1)??methyl]??tosylat und endo??Bicyclo [3.3. 1] nonyl??(2)??tosylat

M Hanack, W Kraus, W Rothenwöhrer…

Index: Hanack,M. et al. Justus Liebigs Annalen der Chemie, 1967 , vol. 703, p. 44 - 65

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Citation Number: 13

Abstract

Abstract [Cycloocten-(4)-yl-(1)-methyl]-tosylat (8, X= OTs) solvolysiert in allen untersuchten Lösungsmitteln unter Beteiligung der Doppelbindung ausschließlich zu exo-und endo- Bicyclo [3.3. 1] nonyl-(2)-, Bicyclo [3.3. 1] nonyl-(3)-und Bicyclo [4.2. 1] nonyl-(2)-Derivaten, die auch bei den Solvolysen von endo-Bicyclo [3.3. 1]-nonyl-(2)-tosylat (14, X= OTs) unter verschiedenen Bedingungen gefunden werden. Der nicht-stereospezifische Verlauf der ...

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