Stereoselective epoxidation of 3??trans??benzylideneisoborneol
YS Sanghvi, AS Rao
Index: Sanghvi, Y. S.; Rao, A. S. Journal of Heterocyclic Chemistry, 1984 , vol. 21, p. 317 - 320
Full Text: HTML
Citation Number: 7
Abstract
Abstract 2-Benzylidenecyclopentanol (2) can be epoxidized stereoselectively to furnish 2- trans-benzylidene-1β-hydroxycyclopentane β-oxide (4) with either t-butyl hydroperoxide in the presence of vanadium catalyst or m-chloroperoxybenzoic acid. Epoxidation of 3-trans- benzylideneisoborneol (10) with t-butyl hydroperoxidevanadium catalyst furnishes stereoselectively 3-trans-benzylideneisoborneol exo-oxide (11) whereas epoxidation of ...
Related Articles:
[Chen, Zhao; Liang, Jinhua; Yin, Jun; Yu, Guang-Ao; Liu, Sheng Hua Tetrahedron Letters, 2013 , vol. 54, # 43 p. 5785 - 5787]
[Roman,S.A.; Closson,W.D. Journal of the American Chemical Society, 1969 , vol. 91, # 7 p. 1701 - 1709]
[Kondo, Teruyuki; Kajiya, Satoshi; Tantayanon, Supawan; Watanabe, Yoshihisa Journal of Organometallic Chemistry, 1995 , vol. 489, # 1-2 p. 83 - 92]