Olefins and Diolefins from Allylic Chlorides

AL Henne, H Chanan, A Turk

Index: Henne; Chanan; Turk Journal of the American Chemical Society, 1941 , vol. 63, p. 3475

Full Text: HTML

Citation Number: 29

Abstract

Irrespective of cis-trans isomkism, which will not be considered here, most allylic chlorides exist in two forms. Crotyl chloride, for instance, is a mixture of a primary chloride, CH3CH= CHCHa-C1, and a secondary chloride, CHz= CHCHClCHa. This permits the synthesis of two olefins by the reaction with a Grignard derivative, three diolefins by condensation on magnesium, or ten diolefins by condensation of two different allylic halides. In practice ...

Related Articles:

Palladium nanoparticles stabilized by alkylated polyethyleneimine as aqueous biphasic catalysts for the chemoselective stereocontrolled hydrogenation of alkenes

[Vasylyev, Maxym V.; Maayan, Galia; Hovav, Yonathan; Haimov, Adina; Neumann, Ronny Organic Letters, 2006 , vol. 8, # 24 p. 5445 - 5448]

Free-radical-mediated carbonylative cyclisation of alk-4-enyl halides leading to cyclopentanones

[Ryu, Ilhyong; Kusano, Kazuya; Hasegawa, Mitsuharu; Kambe, Nobuaki; Sonoda, Noboru Journal of the Chemical Society, Chemical Communications, 1991 , # 15 p. 1018 - 1019]

Tungsten Wittig reagents: an efficient synthesis of α-functionalised tri-and tetrasubstituted alkenes

[Aguero, A.; Kress, J.; Osborn, J. A. Journal of the Chemical Society, Chemical Communications, 1986 , # 7 p. 531 - 533]

The reaction of 1-chloro-2-methyl-1-propenyllithium with a selection of organolithiums. The development and synthetic utility of novel base/nucleophile combinations

[Nelson, Donna J.; Nagarajan, Ananthanarayanan Journal of Organometallic Chemistry, 1993 , vol. 463, # 1-2 p. 1 - 6]

The reaction of 1-chloro-2-methyl-1-propenyllithium with a selection of organolithiums. The development and synthetic utility of novel base/nucleophile combinations

[Nelson, Donna J.; Nagarajan, Ananthanarayanan Journal of Organometallic Chemistry, 1993 , vol. 463, # 1-2 p. 1 - 6]

More Articles...