NAD (P)+-NAD (P) H models. 55. Transition metal catalyzed reduction of organic halides: high selectivity for reductive dehalogenation

S Yasui, K Nakamura, M Fujii…

Index: Yasui, Shinro; Nakamura, Kaoru; Fujii, Masayuki; Ohno, Atsuyoshi Journal of Organic Chemistry, 1985 , vol. 50, # 18 p. 3283 - 3287

Full Text: HTML

Citation Number: 27

Abstract

Various types of aryl, benzyl, vinyl, phenacyl, and allyl halides were subjected to reaction with N-benzyl-1, 4dihydronicotinamide (BNAH), in the presence of a catalytic amount of chlorotris (triphenylphmphine) rhodium (I) or palladium (I1) acetate. The carbon-halogen bonds in these compounds were selectively reduced to the carbon-hydrogen bonds in moderate to excellent yield. This new kind of reduction system has synthetic advantages ...

Related Articles:

Three??Phase Microemulsion/Sol??Gel System for Aqueous Catalytic Hydroformylation of Hydrophobic Alkenes

[European Journal of Organic Chemistry, , # 17 p. 3640 - 3642]

Facile deallylation protocols for the preparation of N-unsubstituted triazoles and tetrazoles

[Kamijo, Shin; Huo, Zhibao; Jin, Tienan; Kanazawa, Chikashi; Yamamoto, Yoshinori Journal of Organic Chemistry, 2005 , vol. 70, # 16 p. 6389 - 6397]

Synthesis of olefins by nickel-catalyzed decarbonylation of S-(2-pyridyl) thioates.

[Goto, Toshio; Onaka, Makoto; Mukaiyama, Teruaki Chemistry Letters, 1980 , p. 709 - 712]

Reduction by a model of NAD (P) H. 44. Transition metal catalyzed reduction of allylic acetate

[Tetrahedron Letters, , vol. 24, # 32 p. 3335 - 3336]

Hydroboration. 86. Convenient conversion of aldehydes and ketones into the corresponding alkenes via hydroboration of their enamines. A remarkably simple …

[Journal of Organic Chemistry, , vol. 56, # 4 p. 1543 - 1549]

More Articles...