Journal of organometallic chemistry

The reactions of acylferrocenes with samarium diiodide: reduction, deoxygenation, reductive coupling and rearrangement

SJ Jong, JM Fang, CH Lin

Index: Jong, Shean-Jeng; Fang, Jim-Min; Lin, Chun-Hsu Journal of Organometallic Chemistry, 1999 , vol. 590, # 1 p. 42 - 45

Full Text: HTML

Citation Number: 12

Abstract

Acylferrocenes reacted with samarium diiodide in the presence of water to give the corresponding (α-hydroxyalkyl) ferrocenes or alkylferrocenes depending on the reaction time and temperature. On treatment with samarium diiodide in the absence of water, ferrocenecarbaldehyde underwent a reductive coupling to give pinacols, whereas acetylferrocene yielded 3, 3-diferrocenyl-2-butanone and 2, 3-diferrocenyl-2-butene via ...

Related Articles:

Palladium-catalyzed reaction of 2-iodoferrocenyl alcohols with internal alkynes: Synthesis of functionally 1, 2-disubstituted ferrocenes and ferroceno-pyrans

[Yucel, Baris; Sanli, Bahar; Soylemez, Huseyin; Akbulut, Huseyin Journal of Organometallic Chemistry, 2012 , vol. 704, p. 49 - 64]

Synthesis and structure of biologically active ferrocenylalkyl polyfluoro benzimidazoles

[Snegur, Lubov' V.; Boev, Victor I.; Nekrasov, Yury S.; Ilyin, Mikhail M.; Davankov, Vadim A.; Starikova, Zoya A.; Yanovsky, Alexander I.; Kolomiets, Alexey F.; Babin, Valery N. Journal of Organometallic Chemistry, 1999 , vol. 580, # 1 p. 26 - 35]

Electrochemical detection of saccharides by the redox cycle of a chiral ferrocenylboronic acid derivative: a novel method for sugar sensing

[Ori, Aiichiro; Shinkai, Seiji Journal of the Chemical Society, Chemical Communications, 1995 , # 17 p. 1771 - 1772]

ALPHA-FERROCENYLATION OF TETRAZOLE AND ITS 1-SUBSTITUTED DERIVATIVES IN TWO-PHASE SYSTEMS

[Russian Journal of General Chemistry, , vol. 67, # 8 p. 1299 - 1305]

ALPHA-FERROCENYLATION OF TETRAZOLE AND ITS 1-SUBSTITUTED DERIVATIVES IN TWO-PHASE SYSTEMS

[Russian Journal of General Chemistry, , vol. 67, # 8 p. 1299 - 1305]

More Articles...