The effect of encapsulated Zn-POM on the catalytic activity of MIL-101 in the oxidation of alkenes with hydrogen peroxide

…, V Mirkhani, I Mohammadpoor-Baltork

Index: Saedi, Zahra; Tangestaninejad, Shaharm; Moghadam, Majid; Mirkhani, Valiollah; Mohammadpoor-Baltork, Iraj Journal of Coordination Chemistry, 2012 , vol. 65, # 3 p. 463 - 473

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Citation Number: 7

Abstract

Zinc monosubstituted Keggin heteropolyanion [PZnMo2W9O39] 5− was electrostatically bound to nanocages of MIL-101 polymer matrix. The Zn-POM@ MIL-101 catalyst was characterized by XRD, N2 adsorption, atomic absorption (AAS), and FT-IR spectroscopic methods. The catalytic activity of the new composite material, Zn-POM@ MIL-101, was assessed in the oxidation of alkenes using aqueous hydrogen peroxide as oxidant. Zn- ...

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