The Journal of organic chemistry

Regioselective oxygenations of S-trans dienes, silyl dienol ethers (SDEs), by triphenyl phosphite ozonide (TPPO) and its mechanistic study

A Mori, M Abe, M Nojima

Index: Abe, Manabu; Inakazu, Tomoyasu; Munakata, Johichi; Nojima, Masatomo Journal of the American Chemical Society, 1999 , vol. 121, # 28 p. 6556 - 6562

Full Text: HTML

Citation Number: 8

Abstract

The direct oxygenation of s-trans dienes, silyl dienol ethers (SDEs) 2, by triphenyl phosphite ozonide (TPPO) has been examined in detail. The regioselective oxygenation was found to give hydroperoxide 3, alcohol 4, ketone 5, dimer 6, and peroxy phosphate 7 with

Related Articles:

Clean and selective oxidation of aromatic alcohols using silica-supported Jones' reagent in a pressure-driven flow reactor

[Wiles, Charlotte; Watts, Paul; Haswell, Stephen J. Tetrahedron Letters, 2006 , vol. 47, # 30 p. 5261 - 5264]

Indium metal as a reducing agent in organic synthesis

[Pitts; Harrison; Moody Journal of the Chemical Society. Perkin Transactions 1, 2001 , # 9 p. 955 - 977]

Regioselective hydration of alkynes by iron (III) Lewis/Brønsted catalysis

[Cabrero-Antonino, Jose R.; Leyva-Perez, Antonio; Corma, Avelino Chemistry - A European Journal, 2012 , vol. 18, # 35 p. 11107 - 11114]

Direct synthesis of arylketones by nickel-catalyzed addition of arylboronic acids to nitriles

[Wong, Ying-Chieh; Parthasarathy, Kanniyappan; Cheng, Chien-Hong Organic Letters, 2010 , vol. 12, # 8 p. 1736 - 1739]

Green oxidations. The use of potassium permanganate supported on manganese dioxide

[Shaabani, Ahmad; Mirzaei, Peiman; Naderi, Soheila; Lee, Donald G. Tetrahedron, 2004 , vol. 60, # 50 p. 11415 - 11420]

More Articles...