Synthesis and decomposition of E-and Z-3, 3, 5-trisubstituted 1, 2-dioxolanes

…, M Miura, M Nojima, S Kusabayashi

Index: Yoshida; Miura; Nojima; Kusabayashi Journal of the American Chemical Society, 1983 , vol. 105, # 20 p. 6279 - 6285

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Citation Number: 22

Abstract

Abstract: The reactions of a number of ozonides and olefins in the presence of boron trifluoriddiethyl ether gave the corresponding mixtures of (E)-and (Z)-1, 2-dioxolanes in 12- 70% yield. The decomposition of the EZ isomeric 1, 2-dioxolanes 3a-c was undertaken under a variety of conditions, Le., thermal, TiC14-mediated, FeSO,-catalyzed, and LiA1H4- mediated decompositions.

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