Journal of fluorine chemistry

On the reactions of dimethylsulfoxide with acyl fluorides-pummerer rearrangements and formation of monofluoromethyl esters

HG Lange, MS Jean'ne

Index: Lange,H.G.; Shreeve,J.M. Journal of Fluorine Chemistry, 1985 , vol. 28, p. 219

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Citation Number: 6

Abstract

Abstract In stoichiometry-dependent reactions, dimethylsulfoxide (DMSO) reacts with acyl fluorides, R f C (O) F (R f= F, CF 3), to yield CH 3 SCH 2 F and R f C (O) OCH 2 F, while CH 3 SCH 2 Cl and FC (O) OCH 2 Cl are obtained with COClF. Oxalyl difluoride, C 2 O 2 F 2, reacts with DMSO to give CH 3 SCH 2 F and FCH 2 OCH 2 F.

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