Tetrahedron

Pd (II)-catalyzed C (sp 2)–H carbonylation of biaryl-2-amine: synthesis of phenanthridinones

Z Liang, J Zhang, Z Liu, K Wang, Y Zhang

Index: Liang, Zunjun; Zhang, Jitan; Liu, Zhanxiang; Wang, Kai; Zhang, Yuhong Tetrahedron, 2013 , vol. 69, # 31 p. 6519 - 6526

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Citation Number: 36

Abstract

A Pd (OAc) 2-catalyzed C (sp2)–H carbonylation protocol of arenes under carbon monoxide atmosphere has been developed. The scope of the carbonylation reaction is broad and tolerates a variety of useful functional groups. This reaction provides a novel and efficient method for the synthesis of biologically and pharmaceutically significant phenanthridinones.

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