Journal für Praktische Chemie

Zur Kenntnis der katalytischen Dimerisation von Acrylsäurederivaten mit Hilfe von Palladiumkomplexen. IV. Zur Dimerisation von Methyl??methacrylat

G Oehme

Index: Oehme, G. Journal fuer Praktische Chemie (Leipzig), 1984 , vol. 326, # 5 p. 779 - 790

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Citation Number: 20

Abstract

Abstract. Methyl methacrylate has been dimerized to a mixture of 2.5-di (methoxycarbony1)- hex-1-ene (1) and (E)-2. b-di (rnethoxycarbonyl)-hex-2-ene (2) by catalytic systems containing dichlorobis (nitrile)-palladium (I1) complexes and silver tctrafluoroborate. Codiinerization experiments with methyl acrylate show a lower reactivity of methyl methacrylate. Oxidative addition of P-chloro methyl methacrylate to tetrakis ( ...

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