Reaction of Aromatic Radical Cations with RuCl 3· 3H 2 O

M Michman, M Oron, HJ Schaefer

Index: Michman, Michael; Oron, Miriam; Schaefer, Hans J. Collection of Czechoslovak Chemical Communications, 2000 , vol. 65, # 6 p. 924 - 940

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Citation Number: 3

Abstract

Abstract Interactions of RuCl 3· 3H 2 O with radical cations of aromatic ethers, 1, 4-di-tert- butyl-2, 5-dimethoxybenzene, 3, 5-di-tert-butyl-1, 2-dimethoxybenzene and 2-tert-butyl-1, 4- di-methoxybenzene, and with aromatic amines, 2, 4, 6-tri-tert-butylaniline and N, N, N', N'- tetra-methyl-1, 4-phenylenediamine, were observed by voltammetry. ESR and UV spectroscopies were used for the study of the the first two ethers. The effect of RuCl 3· 3H ...