The Journal of Organic Chemistry

Jacobsen-type rearrangements in aromatic trichloromethylations

H Hart, JF Janssen

Index: Hart,H.; Janssen,J.F. Journal of Organic Chemistry, 1970 , vol. 35, p. 3637 - 3641

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Citation Number: 12

Abstract

Each compound 7 was added, in CC1, solution, to a twofold excess of A1C13 slurried in CC14, at 40". After 2 hr the trichloromethyl compounds were isolated and methanolyzed, and the resulting methyl esters were separated (vpc), analyzed, and identified by comparison with authentic samples. Isolated yields of esters were 90% or greater; no tars or undesirable side products were produced.