Hydrolysis of 4-nitrophenyl phenyl (trichloromethyl) phosphinate: predominance of a phosphorus-carbon vs. phosphorus-oxygen bond cleavage reaction

PS Hammond, MB Kirchner…

Index: Journal of Organic Chemistry, , vol. 55, # 24 p. 6049 - 6051

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Citation Number: 4

Abstract

... This novel bond scission could find utility in conven- tional synthetic organic chemistry and in transformations of sensitive compounds of biological importance. For ex- ample, in the preparation of nucleoside 3',5'-cyclic phos- phates. ... (b) Flowers, H. M.; Jeanloz, RW J. Org. Chem. ...