2, 4-Methano-2, 4-dehydroadamantane. A [3.1. 1] propellane

K Mlinaric-Majerski, Z Majerski

Index: Mlinaric-Majerski,K.; Majerski,Z. Journal of the American Chemical Society, 1980 , vol. 102, p. 1418

Full Text: HTML

Citation Number: 26

Abstract

In this case one now anticipates, and finds, an isotope discrimination. Again, using the formalism of the perepoxide for purposes of discussion, one sees that, in 7, the system has a choice of abstracting D from the chiral center or reacting with methyl CH bonds and, in 8, a choice of-H or the methyl CH. We find an isotope effect of 1.2. This is exactly half the effect (1.4) found for the system 9, which is ideally suited for 1 a 2 cis competition on both top ...

Related Articles:

Contribution à l'étude des réactions d'alkylation et de polyalkylation de l'adamantane et de ses homologues

[Canadian Journal of Chemistry, , vol. 65, p. 2428 - 2433]

Hydrogenolysis of alkyl??substituted adamantanes, diamantanes, and triamantanes in the gas phase on a nickel??alumina catalyst

[Chemische Berichte, , vol. 113, # 5 p. 1989 - 2006]

Hydrogenolysis of alkyl??substituted adamantanes, diamantanes, and triamantanes in the gas phase on a nickel??alumina catalyst

[Chemische Berichte, , vol. 113, # 5 p. 1989 - 2006]

Hydrogenolysis of alkyl??substituted adamantanes, diamantanes, and triamantanes in the gas phase on a nickel??alumina catalyst

[Chemische Berichte, , vol. 113, # 5 p. 1989 - 2006]

Hydrogenolysis of alkyl??substituted adamantanes, diamantanes, and triamantanes in the gas phase on a nickel??alumina catalyst

[Chemische Berichte, , vol. 113, # 5 p. 1989 - 2006]

More Articles...