Synlett

Asymmetric hydrosilylation of alkenes with alkoxyhydrosilanes catalyzed by chiral bis (oxazolinyl) phenyl-rhodium complex

Y Tsuchiya, H Uchimura, K Kobayashi, H Nishiyama

Index: Tsuchiya, Yasunori; Uchimura, Hirofumi; Kobayashi, Kazuki; Nishiyama, Hisao Synlett, 2004 , # 12 p. 2099 - 2102

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Citation Number: 18

Abstract

Chiral 2,6-bis(2-oxazolinyl)phenyl skeleton (abbreviated as Phebox) has been developed as a C 2 -symmetric pincer ligand for transition metal complexes, which exhibit its high potentiality in several high stereo- and enantioselective catalysis. [1] [2] In this report, we describe an efficient application of Rh-Phebox complex 1 to asymmetric hydrosilylation of alkenes (AHSA). In this context, several chiral rhodium catalysts were so far applied only to the intermolecular ...

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