A bimetallic system for the catalytic hydroxylation of remote primary CH bonds in functionalized organics using dioxygen

C Shen, EA Garcia-Zayas, A Sen

Index: Shen, Chengyu; Garcia-Zayas, Eduardo A.; Sen, Ayusman Journal of the American Chemical Society, 2000 , vol. 122, # 17 p. 4029 - 4031

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Citation Number: 33

Abstract

In a mixture of trifluoroacetic acid and water, the combination of metallic palladium and copper chloride catalyzes the hydroxylation of remote primary CH bonds of a variety of acids, alcohols, and aliphatic halides, in the presence of carbon monoxide and dioxygen. Experiments suggest that the principal role of metallic palladium is to generate hydrogen peroxide in situ and that the species responsible for the remote hydroxylation of the ...

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