Tetrahedron Letters

First examples of superelectrophile initiated iodination of alkanes and cycloalkanes

I Akhrem, A Orlinkov, S Vitt, A Chistyakov

Index: Akhrem, Irena; Orlinkov, Alexander; Vitt, Sergei; Chistyakov, Anatolii Tetrahedron Letters, 2002 , vol. 43, # 7 p. 1333 - 1335

Full Text: HTML

Citation Number: 11

Abstract

Elaboration of one-pot selective transformations of alkanes and cycloalkanes into their functionalized derivatives is a topic of current interest. 1., , , , , and In recent years, topics for study have become not only thermodynamically favorable reactions of alkanes but also those occurring with consumption of energy. 2., 3., 4., , and 5. Iodination of saturated hydrocarbons is an example of this type of reaction. ... E t =−105.3 (E t 0 =−106.5), X=F; −28.5 (−31.0), X=Cl; −8.9 (−12.3), X=Br; ...

Related Articles:

Synthesis of chlorinated and brominated biphenyl oxides

[Olah, George A.; Narang, Subhash C.; Field, Leslie D. Journal of Organic Chemistry, 1981 , vol. 46, # 18 p. 3727 - 3728]

Reduction of benzylic alcohols and α-hydroxycarbonyl compounds by hydriodic acid in a biphasic reaction medium

[Dobmeier, Michael; Herrmann, Josef M.; Lenoir, Dieter; Koenig, Burkhard Beilstein Journal of Organic Chemistry, 2012 , vol. 8, p. 330 - 336]

Synthesis of chlorinated and brominated biphenyl oxides

[Olah, George A.; Narang, Subhash C.; Field, Leslie D. Journal of Organic Chemistry, 1981 , vol. 46, # 18 p. 3727 - 3728]

The first efficient iodination of unactivated aliphatic hydrocarbons

[Angewandte Chemie - International Edition, , vol. 38, # 18 p. 2786 - 2788]

Synthetic methods and reactions. 113. Reactions of nitro-and nitrosoalkanes with iodotrimethylsilane

[Journal of Organic Chemistry, , vol. 48, # 16 p. 2766 - 2767]

More Articles...