Oxidation of Alkenes and Sulfides with Transition Metal Catalysts

…, KY Cheng, JM Fang, MC Cheng…

Index: Liao, Jen-Hai; Cheng, Kuang-Yuan; Fang, Jim-Min; Cheng, Ming-Chu; Wang, Yu Journal of the Chinese Chemical Society (Taipei, Taiwan), 1995 , vol. 42, # 5 p. 847 - 860

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Citation Number: 10

Abstract

Abstract Alkenes and sulfides were oxidized with transition-metal catalysts. The oxidant sources include molecular dioxygen, air and iodosylbenzene. The metal ions Mn (III), Fe (III), Co (II) and Ni (II) were used. The Catalysts 1-18 of 1, 3-dioxo-, β-ketoimine-or salen-types were prepared and their efficacy was examined. 1, 2-Dihydronaphthalene is most efficiently epoxidized with O 2/Me 2 CHCHO or PhIO in the presence of Mn (III)-salen catalysts. The ...