A water-compatible, highly active and reusable PEG-coated mesoporous silica-supported palladium complex and its application in Suzuki coupling reactions
Q Yang, S Ma, J Li, F Xiao, H Xiong
Index: Yang, Qing; Ma, Shengming; Li, Jixue; Xiao, Fengshou; Xiong, Hai Chemical Communications, 2006 , # 23 p. 2495 - 2497
Full Text: HTML
Citation Number: 57
Abstract
A highly active heterogeneous palladium catalyst was prepared from coated mesoporous materials which contain a layer of readily available PEG with a labile coordinating ability for palladium. The aqueous suspension of the catalyst may be reused several times by simple extraction of the aqueous reaction mixture with ether to remove the product.
Related Articles:
[Freundlich, Joel S.; Landis, Howard E. Tetrahedron Letters, 2006 , vol. 47, # 25 p. 4275 - 4279]
[Shirini, Farhad; Khaligh, Nader Ghaffari; Akbari-Dadamahaleh, Somayeh Journal of Molecular Catalysis A: Chemical, 2012 , vol. 365, p. 15 - 23]
[Gallon, Benjamin J.; Kojima, Robert W.; Kaner, Richard B.; Diaconescu, Paula L. Angewandte Chemie - International Edition, 2007 , vol. 46, # 38 p. 7251 - 7254]
[Yoshida, Kazuhiro; Imamoto, Tsuneo Journal of the American Chemical Society, 2005 , vol. 127, # 30 p. 10470 - 10471]
[Tetrahedron, , vol. 67, # 52 p. 10156 - 10163]