Tetrahedron Letters

A stereospecific synthesis of conjugated (E, Z)-and (E, E)-alkadienes by the palladium-catalyzed reaction of (E)-1-alkenylboronic acids and 1-alkenyl iodides

G Cassani, P Massardo, P Piccardi

Index: Cassani, G.; Massardo, P.; Piccardi, P. Tetrahedron Letters, 1983 , vol. 24, # 24 p. 2513 - 2516

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Citation Number: 28

Abstract

Abstract The reaction of (E)-1-alkenylboronic acids with (Z)-or (E)-1-alkenyl iodides in the presence of a catalytic amount of tetrakis (triphenylphosphine)-palladium and sodium hydroxide gave the corresponding conjugated (E, Z)-or (E, E)--alkadienes with high stereospecificity.

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