Journal of the American Chemical Society

The Action of Elementary Fluorine upon Organic Compounds. XV. Fluorine and Cobaltic Fluoride as Fluorinating Agents for Ketones1

FF Holub, LA Bigelow

Index: Holub; Bigelow Journal of the American Chemical Society, 1950 , vol. 72, p. 4879,4884

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Citation Number: 17

Abstract

Summary 1. In ethyl alcohol solution diphenyldiazomethane reacts with ethyl alcohol in the presence of an acid catalyst to form ethyl benzhydryl ether. Kinetic studies by a spectrophotometric method have established that this reaction is subject to general acid catalysis. The effects on the rate of inert salt and of increasing concentrations of water in the ethyl alcohol solvent, both when the catalyst is solvated hydrogen ion and undissociated ...

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