Journal of Catalysis

Novel Support Effects on the Mechanism of Propene-Deuterium Addition and Exchange Reactions over Dispersed ZrO 2

S Naito, M Tanimoto

Index: Naito, Shuichi; Tanimoto, Mitsutoshi Journal of Catalysis, 1995 , vol. 154, # 2 p. 306 - 313

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Citation Number: 18

Abstract

The effect on the rate and mechanisms of propene-deuterium reactions of dispersing ZrO2 on various supports such as silica, alumina, and titanium dioxide has been studied by microwave spectroscopic analysis of monodeuteropropene as well as by kinetic investigation. By dispersal of ZrO2 on these supports, the rate of the C3H6-D2 reactions is increased considerbly compared to that over unsupported ZrO2, with the decrease of ...

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