The Journal of Physical Chemistry

Protonation of C3H6 isomers: isotope exchange and isomerization

EP Hunter, SG Lias

Index: Hunter, Edward P.; Lias, S. G. Journal of Physical Chemistry, 1982 , vol. 86, # 14 p. 2769 - 2775

Full Text: HTML

Citation Number: 17

Abstract

Isotope exchange processes of the type (MH'+ C3D6-MD'+ C3HD5) or (MD'+ C3H6-MH'+ C3H5D)(where C3 (H, D) 6 is propylene or cyclopropane) have been studied in an ICR spectrometer. It is shown that, for both reactant molecules, the efficiency of the exchange reaction can be correlated with the exothermicity of the formation of the complex [M. C3 (H, D),+] from separated M (H, D)+ and C3 (H, D) 6 reactants. In the case of propylene, all of ...

Related Articles:

Marked changes of reaction intermediates caused by alloying: deuterium addition and exchange of propene over Ni–Cu, Pd–Cu, and Pt–Cu catalysts

[Naito, Shuichi; Tanimoto, Mitsutoshi Journal of the Chemical Society, Chemical Communications, 1987 , # 5 p. 363 - 365]

Novel Support Effects on the Mechanism of Propene-Deuterium Addition and Exchange Reactions over Dispersed ZrO 2

[Naito, Shuichi; Tanimoto, Mitsutoshi Journal of Catalysis, 1995 , vol. 154, # 2 p. 306 - 313]

Use of simple test reactions to characterise the catalytic activity of a commercial CoO-MoO 3-Al 2 O 3 catalyst

[John, Christopher S.; Williamson, James G.; Kennedy, Lois V. F.; Tyler, J. Kelvin Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1980 , vol. 76, p. 1356 - 1365]

Carbon acidity. 58. Hydrogen isotope exchange kinetics of propylene with lithium cyclohexylamide

[Boerth, Donald W.; Streitwieser, Andrew Jr. Journal of the American Chemical Society, 1981 , vol. 103, # 21 p. 6443 - 6447]

Mechanism of the Decomposition of Silacyclobutane to Silylene and Propene

[Barton,T.J.; Tillman,N. Journal of the American Chemical Society, 1987 , vol. 109, p. 6711]

More Articles...