Synthesis

Highly chemoselective rearrangement of 3-aryloxaziridines to nitrones or amides

D Xing, X Xu, L Yang

Index: Xing, Dong; Xu, Xinfang; Yang, Liping Synthesis, 2009 , # 20 p. 3399 - 3404

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Citation Number: 6

Abstract

Abstract An efficient method for the chemoselective ring-opening rearrangement of 3- aryloxaziridines by using silver triflate alone to afford nitrones, or in the presence of a simple Brønsted acid to yield amides, has been developed. Silver triflate plays an important role in both transformations.

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