Ruthenium-catalyzed linear selective allylic aminations of monosubstituted allyl acetates

M Kawatsura, F Ata, T Hirakawa, S Hayase, T Itoh

Index: Kawatsura, Motoi; Ata, Fumio; Hirakawa, Takuya; Hayase, Shuichi; Itoh, Toshiyuki Tetrahedron Letters, 2008 , vol. 49, # 33 p. 4873 - 4875

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Citation Number: 28

Abstract

The ruthenium-catalyzed highly linear selective allylic amination of monosubstituted allylic acetates with secondary amines was developed. The regioselectivity was controlled by the Ru3 (CO) 12/2-DPPBA catalyst, and a linear-type aminated product was obtained as a single regioisomer.