Organometallics

Chemistry of octacarbonyl-. mu.-methylenediiron and its derivatives

CE Sumner Jr, JA Collier, R Pettit

Index: Sumner, Charles E.; Collier, Joseph A.; Pettit, R. Organometallics, 1982 , vol. 1, p. 1350 - 1360

Full Text: HTML

Citation Number: 64

Abstract

The reaction of the Fe2 (CO) $-dianion with methylene iodide leads to the formation of the parent bridging methylene complex, octacarbonyl (p-methylene) diiron, Fe,(CO) &H,. The reaction appears to be general and several derivatives have been prepared by using other geminal diiodides. The bridging methylene complexes react with unsaturated reactants such as olefins and acetylenes to produce new organometallic complexes in which the ...

Related Articles:

Sonochemistry and sonocatalysis of metal carbonyls

[Suslick, Kenneth S.; Goodale, James W.; Schubert, Paul F.; Wang, Hau H. Journal of the American Chemical Society, 1983 , vol. 105, # 18 p. 5781 - 5785]

Cyclopentannulation reactions with organoiron reagents. Facile construction of functionalized hydroazulenes

[Rosenblum; Watkins Journal of the American Chemical Society, 1990 , vol. 112, # 17 p. 6316 - 6322]

Trialkylbismutine als Liganden in Carbonylkomplexen des Eisens und der VIa??Elemente

[Breunig, H. J.; Graefe, U. Zeitschrift fuer Anorganische und Allgemeine Chemie, 1984 , vol. 510, p. 104 - 108]

Sonochemistry and sonocatalysis of iron carbonyls

[Suslick, Kenneth S.; Schubert, Paul F.; Goodale, James W. Journal of the American Chemical Society, 1981 , vol. 103, # 24 p. 7342 - 7344]

Synthesis of Blue Imino (pentafluorophenyl) phosphane

[Kuprat, Marcus; Lehmann, Mathias; Schulz, Axel; Villinger, Alexander Inorganic Chemistry, 2011 , vol. 50, # 12 p. 5784 - 5792]

More Articles...