Synthesis

New methods for the syntheses of α, β-unsaturated ketones, aldehydes, and nitriles by the palladium-catalyzed reactions of allyl β-oxo esters, allyl 1-alkenyl …

I Minami, M Nisar, M Yuhara, I Shimizu, J Tsuji

Index: Minami, Ichiro; Nisar, Mohammad; Yuhara, Masami; Shimizu, Isao; Tsuji, Jiro Synthesis, 1987 , # 11 p. 992 - 998

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Citation Number: 25

Abstract

Tokyo Institute 01'lca 'lini\ tii> 1. _:}.~'. _\/lcgllro. Tokyo I52. I: ip: m,~\ llyl;'='-ow esters. ally! l zilltmjvl c; irho11alcs, and; ill) l 24}./11111,»<-stun: u" u conwrlcd inn: a.! i-\ ii': i: 1lu1'ai1cnl i£ t.'lOl1OS. auldcliydcs,: 1 ml; 1itrilr'~ by palludiulnczitulyzlcil inlnamolcculzii 'dcczirhoxylziiicwii-cluliyiliogcimlion. Pnlladium--phosphinc con. plc. xc> such HS Pd (() f\ c);,- l" l'l1,;. l'd (_ ();\ c);-dppu, or Pdztdh-a) _,~(_1ll ('I_,~ Pl'h_K arc cllL* ctiv: cailzzlysts. Yiuhls ...

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