Asymmetric electrochemical lactonization of diols on a chiral 1-azaspiro [5.5] undecane N-oxyl radical mediator-modified graphite felt electrode

Y Kashiwagi, F Kurashima, S Chiba, J Anzai…

Index: Kashiwagi, Yoshitomo; Kurashima, Futoshi; Chiba, Shinya; Anzai, Jun-Ichi; Osa, Tetsuo; Bobbitt, James M. Chemical Communications, 2003 , # 1 p. 114 - 115

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Citation Number: 20

Abstract

A graphite felt electrode modified with (6S, 7R, 10R)-4-amino-2, 2, 7-trimethyl-10-isopropyl-1- azaspiro [5.5] undecane N-oxyl was prepared for electrocatalytic oxidation of diols; electrolysis of diols on the modified electrode yielded optically active lactones (92.0–96.4%), with an enantiopurity of 82–99% ee.

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